کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1820172 | 1525779 | 2007 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Raman analysis of asymmetrical chains in YBa2Cu3O7âδ films
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موضوعات مرتبط
مهندسی و علوم پایه
فیزیک و نجوم
فیزیک ماده چگال
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چکیده انگلیسی
YBa2Cu3O7âδ/MgO(1 0 0) thin films with depletion of oxygen have been studied with Raman spectroscopy. The depletion changes the intensity of 233 and 596 cmâ1 phonons induced from Cu(1)-O(1) asymmetrical chains. A simple model of a symmetry-broken chain row is introduced to explain this phenomenon. With depletion, the row is configured as asymmetrical [O(1)-Cu(1)-o(1)] chains, where O(1) and o(1) are full and deficient oxygen in the orthorhombic and tetragonal structures, respectively. The Raman peaks at 233 and 596 cmâ1 increase with an increase in a population density of the asymmetrical chains in the row and decrease as the row has more symmetric sites of full or deficient oxygen. As a result, the intensity of the chain-induced modes reflects a degree of the opposite structure involved in the phase transition in a single-phase film, which is verified by both the relative intensity of the 232 cmâ1 phonon and the full width at half maximum of a Cu(2) superposition band from the coexisting phases in the film. All the results support the asymmetrical-chain model.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Physica C: Superconductivity - Volume 454, Issues 1â2, 15 April 2007, Pages 82-87
Journal: Physica C: Superconductivity - Volume 454, Issues 1â2, 15 April 2007, Pages 82-87
نویسندگان
Seongsik Hong, Kyungmoon Kim, Hyeonsik Cheong, Gwangseo Park,