کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1848086 | 1033457 | 2007 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Radiation synthesis and characteristics of PTFE-g-PSSA ion exchange membrane applied in vanadium redox battery
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
فیزیک و نجوم
فیزیک هسته ای و انرژی بالا
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Radiation-induced grafting of styrene onto polytetrafluoroethylene (PTFE) membranes was studied by a simultaneous irradiation technique. Grafting was carried out using γ - radiation from a 60Co source at room temperature. Effects of absorbed dose, atmosphere, dose rate, and the concentration of initial monomer on the degree of grafting (DOG) were investigated and the most appropriate grafting condition was obtained. Subsequently, sulphonation of the grafted PTFE membrane (PTFE-g-PS) was carried out and a series of ion exchange membranes (PTFE-g-PSSA) was prepared. Further characterizations of FTIR, TGA, and SEM testified that grafting and sulphonation of the membranes were successfully processed; moreover, grafting of styrene not only occurred in the surface of PTFE membrane, but also in the micropores of the membrane. Ion exchange capacity (IEC) and conductivity were found increase with the grafting yield. The results suggest that at a low dose, such as 17 kGy, the ion exchange membrane (IEM) which will be suitable for vanadium redox battery (VRB) use can be obtained.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Nuclear Science and Techniques - Volume 18, Issue 1, February 2007, Pages 50-54
Journal: Nuclear Science and Techniques - Volume 18, Issue 1, February 2007, Pages 50-54
نویسندگان
PENG Jinfen, QIU Jinyi, NI Jiangfeng, ZHAI Maolin, XU Peng, PENG Jing, ZHOU Henghui, LI Jiuqiang, WEI Genshuan,