کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1886482 | 1043527 | 2012 | 4 صفحه PDF | دانلود رایگان |
New multiwalled carbon nanotube/silica supported cobalt-palladium bimetallic nanocatalysts (MWNT@silica/Co–Pd NPs) were prepared by a simple one step gamma irradiation method. The method involves the in-situ surface modification of MWNT with silica (MWNT@silica) and simultaneous formation of Co–Pd bimetallic NPs using gamma irradiation. The bimetallic NPs were stabilized by silica particles formed over the surface of MWNT. Extensive characterization studies have been performed on structural, morphological, and electrochemical, aspects of MWNT@silica/Co–Pd NPs. MWNT@silica/Co–Pd NPs were characterized by field emission scanning microscopy (FESEM), UV–visible spectroscopy, X-ray diffraction (XRD), thermogravimetric analysis (TGA), and Raman spectroscopy. The influence of irradiation dosage levels on the stabilizing effect of silica particles has been studied. The electrolytic activities of the MWNT@silica/Co–Pd NPs were investigated by cyclic voltammetry.
► New supported cobalt–palladium bimetallic nanocatalysts were prepared.
► Structural, morphological and electrochemical properties are reported.
► Electrocatalytic reduction of oxygen has been demonstrated for the new catalysts.
Journal: Radiation Physics and Chemistry - Volume 81, Issue 9, September 2012, Pages 1422–1425