کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
201521 460554 2015 13 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Extraction of nitrogen compounds from diesel fuel using imidazolium- and pyridinium-based ionic liquids: Experiments, COSMO-RS prediction and NRTL correlation
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Extraction of nitrogen compounds from diesel fuel using imidazolium- and pyridinium-based ionic liquids: Experiments, COSMO-RS prediction and NRTL correlation
چکیده انگلیسی

1-Ethyl-3-methylimidazolium ethyl sulfate ([EMIM][EtSO4]), 1-ethyl-3-methylpyridinium ethyl sulfate ([EMPY][EtSO4]) and 1-ethyl-3-methylimidazolium methanesulfonate ([EMIM][MeSO3]) ionic liquids were investigated to remove pyrrole, indoline, pyridine and quinoline nitrogen compounds from n-hexadecane. Twelve sets of ternary liquid–liquid equilibrium experiments were conducted at room temperature and atmospheric pressure with feed concentrations of nitrogen compounds ranging between 5 and 50 wt%. The ternary phase diagrams for all systems show positive slope, indicating that small amount of solvent is sufficient to remove the nitrogen compounds. Based on the values of distribution coefficient and selectivity, all three ionic liquids are potential solvents for removal of nitrogen compounds, but more effective in removing 5-membered compounds (pyrrole, indoline) than 6-membered compounds (pyridine and quinoline). COSMO-RS predictions of the ternary tie-lines were in good agreement with experimental results (RMSD < 5%). The experimental data were also correlated using the NRTL model with excellent agreement (RMSD < 1%).

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Fluid Phase Equilibria - Volume 405, 15 November 2015, Pages 55–67
نویسندگان
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