کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
202021 | 460581 | 2012 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
The critical temperature and properties of real gas from low order perturbed virial expansions
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: The critical temperature and properties of real gas from low order perturbed virial expansions The critical temperature and properties of real gas from low order perturbed virial expansions](/preview/png/202021.png)
چکیده انگلیسی
It is shown that a low-order expansion in powers of density about a short-range reference system, called a perturbed virial expansion, is superior to the common virial expansion and provides a reasonably accurate estimate of both the critical temperature of simple fluids and results on thermodynamics of real gas over a wider range of densities/temperatures. The results are presented for three common van der Waals hard-core models (square-well, Yukawa, and Sutherland) and for the realistic Lennard-Jones fluid.
► Extension of applicability of the virial expansion.
► Estimation of the critical temperature from the 2nd virial coefficient only.
► Correction of the ideal gas behavior at higher densities.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Fluid Phase Equilibria - Volume 314, 25 January 2012, Pages 156–160
Journal: Fluid Phase Equilibria - Volume 314, 25 January 2012, Pages 156–160
نویسندگان
J. Krejčí, I. Nezbeda,