Isothermal VLE measurements for the binary mixture of 2,3,3,3-tetrafluoroprop-1-ene (HFO-1234yf) + 1,1-difluoroethane (HFC-152a)

• Experimental VLE data for HFO-1234yf + HFC-152a were reported.
• The mixture exhibits azeotropic and near azeotropic behaviors.
• Temperature glide is less than 0.4 K within the complete range of composition.

Isothermal vapor–liquid equilibrium (VLE) data for the binary mixture of 2,3,3,3-tetrafluoroprop-1-ene (HFO-1234yf) + 1,1-difluoroethane (HFC-152a) were measured at temperatures from 283.15 K to 323.15 K using a recirculation apparatus. The experimental data were correlated by using PR EoS with vdW mixing rule, the comparison between the correlation results and experimental data showed a good agreement. HFO-1234yf (1) + HFC-152a (2) system shows not only azeotropic behavior but also near azeotropic behavior with a very small temperature glide of less than 0.4 K within the complete range of composition and of temperature.