کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
202800 460622 2010 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Physico-chemical, acoustic and excess properties of glycylglycine–MnCl2 in aqueous ethanol mixtures at different temperatures
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Physico-chemical, acoustic and excess properties of glycylglycine–MnCl2 in aqueous ethanol mixtures at different temperatures
چکیده انگلیسی

Volumetric, acoustic, refractometric, excess and deviation properties of glycylglycine–MnCl2 in aqueous ethanol mixtures have been reported at T = (288.15 to 318.15) K. Redlich–Kister equation was used to fit the derivate properties. The experimental data of the constituent binaries were analyzed to discuss the nature and strengths of intermolecular interactions. The interdependence of Lf and u has been evolved from Eyring and Kincaid model. The variations in specific acoustic impedance revealed that hydrogen bonding was predominant in the studied binary mixtures. Solvation number indicated structure-breaking tendency of the solute and weakening of local solvent structure.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Fluid Phase Equilibria - Volume 291, Issue 2, 15 May 2010, Pages 174–179
نویسندگان
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