کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
203239 | 460643 | 2010 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Development of Abraham model correlations for solvation characteristics of secondary and branched alcohols
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Development of Abraham model correlations for solvation characteristics of secondary and branched alcohols Development of Abraham model correlations for solvation characteristics of secondary and branched alcohols](/preview/png/203239.png)
چکیده انگلیسی
Data have been compiled from the published literature on the partition coefficients of solutes and vapors into the anhydrous secondary and branched alcohols (2-propanol, 2-butanol, 2-methyl-1-propanol, 2-methyl-2-propanol and 3-methyl-1-butanol) from both water and from the gas phase. The logarithms of the water-to-alcohol partition coefficients (log P) and gas-to-alcohol partition coefficients (log K) were correlated with the Abraham solvation parameter model. The derived correlations described the observed log P and log K values to within average standard deviations of 0.14 and 0.13 log units, respectively. The predictive abilities of the each correlation were assessed by dividing databases into a separate training set and test set.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Fluid Phase Equilibria - Volume 288, Issues 1–2, 25 January 2010, Pages 121–127
Journal: Fluid Phase Equilibria - Volume 288, Issues 1–2, 25 January 2010, Pages 121–127
نویسندگان
Laura M. Sprunger, Sai S. Achi, Racheal Pointer, William E. Acree Jr., Michael H. Abraham,