کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
204011 460692 2008 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Prediction of homogeneous azeotropes by Wilson equation for binary HFCs and HCs refrigerant mixtures
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Prediction of homogeneous azeotropes by Wilson equation for binary HFCs and HCs refrigerant mixtures
چکیده انگلیسی

A simple approach based on Newton's method using Wilson activity coefficients equation and Antoine equation is proposed to determine the binary homogeneous azeotropes for hydrofluorocarbons (HFCs) and hydrocarbons (HCs) mixtures. With the known Wilson parameters at a certain temperature, the azeotropic composition at this temperature range can be evaluated. Only one point of the measured VLE data is required to evaluate the Wilson parameters firstly if they are unavailable. The method is verified with six binary systems, which are ethane (HC-170) + trifluoromethane (HFC-23), difluoromethane (HFC-32) + propane (HC-290), pentafluoroethane (HFC-125) + propane (HC-290), 1,1,1,2-tetrafluoroethane (HFC-134a) + n-butane (HC-600), 1,1,1-trifluoroethane (HFC-143a) + n-butane (HC-600) and propane (R290) + 1,1,1,2,3,3,3-heptafluoropropane (R227ea) mixtures. Good agreements are found between the calculated results and reference data.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Fluid Phase Equilibria - Volume 269, Issues 1–2, 25 July 2008, Pages 6–11
نویسندگان
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