Vapor–liquid equilibria for the ternary system of carbon dioxide + ethanol + ethyl acetate at elevated pressures

Vapor–liquid equilibrium (VLE) data for the ternary system of carbon dioxide, ethanol and ethyl acetate were measured in this study at 303.2, 308.2, and 313.2 K, and at pressures from 4 to 7 MPa. A static type phase equilibrium apparatus with visual sapphire windows was used in the experimental measurements. New VLE data for CO2 in the mixed solvent were presented. These ternary VLE data at elevated pressures were also correlated using either the modified Soave–Redlich–Kwong or Peng–Robinson equation of state, with either the van der Waals one-fluid or Huron–Vidal mixing model. Satisfactory correlation results are reported with temperature-independent binary parameters. It is observed that at 313.2 K and 7 MPa, ethanol can be separated from ethyl acetate into the vapor phase at all concentrations in the presence of high pressure CO2.