کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
204648 460769 2008 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Experimental and predicted phase equilibria and excess properties for systems with ionic liquids
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Experimental and predicted phase equilibria and excess properties for systems with ionic liquids
چکیده انگلیسی

Vapor–liquid equilibria (VLE) for the binary systems methylcyclohexane–toluene and 1-octene–n-octane and the ternary systems with the ionic liquid 1-hexyl-3-methyl-imidazolium bis(trifluoro-methylsulfonyl)imide [HMIM]+[BTI]− as entrainer were measured. The addition of the ionic liquid leads to an increase of the separation factors. Excess enthalpies (HE) were measured for methylcyclohexane and n-octane in the same ionic liquid as well. Furthermore activity coefficients at infinite dilution (γ∞) were determined for a few solutes in various ionic liquids such as 1-hexyl-3-methyl-imidazolium bis(trifluoro-methylsulfonyl)imide [HMIM]+[BTI]−, 1-hexyl-3-methyl-imidazolium trifluoro-methanesulfonate [HMIM]+[OTF]−, 1-methyl-1-octyl-pyrrolidinium bis(trifluoromethyl-sulfonyl)imide [MOPYR]+[BTI]−, 1-methyl-1-butyl-pyrrolidinium trifluoromethanesulfonate [MBPYR]+ [OTF]− and 1-ethyl-3-methyl-imidazolium ethyl sulfate [EMIM]+[EtOSO3]−. The γ∞-values were used to determine the selectivities Sij∞=γi∞/γj∞ and the capacities ki=1/γi∞ at infinite dilution. The experimental data with [R1R2IM]+[BTI]− were compared with the predicted results using mod. UNIFAC (Do). The predicted results are in good agreement with the experimental data.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Fluid Phase Equilibria - Volume 268, Issues 1–2, 25 June 2008, Pages 14–20
نویسندگان
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