کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
204687 | 460779 | 2007 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Application of perturbed chain equation-of-state to solid–liquid equilibria: I. Pure component
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Application of perturbed chain equation-of-state to solid–liquid equilibria: I. Pure component Application of perturbed chain equation-of-state to solid–liquid equilibria: I. Pure component](/preview/png/204687.png)
چکیده انگلیسی
A perturbed chain equation-of-state was applied to the solid-fluid equilibria (SFE) of Lennard–Jones (LJ) chains and of n-alkanes with carbon number of 4–32. Results for the LJ chains were reasonable and consistent. The model was able to accurately correlate the SFE of the n-alkanes using parameters that represent segment size, chain length, and intermolecular interaction. Parameters regressed from the n-alkanes varied smoothly and consistently with carbon number. A repulsive exponent in Mie's potential of 40 was found to be optimal. This work sets-up extension of the pure-component model to mixtures.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Fluid Phase Equilibria - Volume 262, Issues 1–2, 15 December 2007, Pages 37–43
Journal: Fluid Phase Equilibria - Volume 262, Issues 1–2, 15 December 2007, Pages 37–43
نویسندگان
T.W. Cochran, Y.C. Chiew,