کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
204858 | 460815 | 2006 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Thermo-chemical properties of aqueous solution containing ionic liquids: 1. The heat of reaction mixed 1-methyl-3-butylimidazolium chloride with InCl3
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The ionic liquid BMIInCl4 was prepared by mixing 1-methyl-3-butylimidazolium chloride (BMIC) with InCl3. The molar solution enthalpies of BMIC and BMIInCl4 at various molalities were determined by the solution reaction isoperibol calorimeter in water at 298.15 K. In terms of Pitzer's electrolyte solution theory, the molar solution enthalpy of BMIC and BMIInCl4 at infinite dilution, ΔsHm° and the parameters: βMX(0)L,βMX(1)L and CMXϕL were obtained. Then the values of apparent relative molar enthalpy ϕL and relative partial molar enthalpies of solute (BMIC and BMIInCl4), L2, were calculated, respectively. In terms of values of ΔsHm° of BMIC, BMIInCl4 and InCl3, the enthalpy change for the reaction: BMIC + InCl3 → BMIInCl4 was obtained.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Fluid Phase Equilibria - Volume 239, Issue 2, 31 January 2006, Pages 161–165
Journal: Fluid Phase Equilibria - Volume 239, Issue 2, 31 January 2006, Pages 161–165
نویسندگان
Wei Guan, Jia-Zhen Yang, Lei Li, Heng Wang, Qing-Guo Zhang,