کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
205332 461105 2016 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Extractive oxidation desulfurization of sulfur-containing model fuel using hexamine–phosphotungstate hybrid as effective heterogeneous catalyst
ترجمه فارسی عنوان
سولفوریزاسیون اکسیداسیون از سوخت مدل با گوگرد با استفاده از هگزامینا فسفودوفرناتات به عنوان کاتالیزور ناهمگن موثر
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
چکیده انگلیسی


• An efficient hybrid catalyst was prepared for oxidative desulfurization.
• The main factors affecting the desulfurization were optimized by Taguchi method.
• The S-content of DBT model oil was decreased from 910 ppmw to 1 ppmw.
• Heterogeneous catalyst is easily recovered by centrifugation and reused.

An organic hybrid of phosphotungstic acid was prepared by using an industrial easy-prepared amine (i.e. hexamine) and characterized by elemental analyses, infrared spectrum, powder X-ray diffraction, thermal analyses, scanning electron microscopy and energy dispersive X-ray spectroscopy. An extractive and catalytic oxidative desulfurization process of sulfur-containing model fuel was studied using hexamine–phosphotungstate hybrid as catalyst, hydrogen peroxide as oxidant and acetonitrile as extractant. The effects of the catalyst dosage and hydrogen peroxide dosage, the reaction time, and the reaction temperature on the removal of dibenzothiophene (DBT) were optimized by Taguchi method. Under the predicted conditions, the removal of DBT achieved 99.91%. The heterogeneous catalyst can be easily recovered and reused by centrifugation. Finally, the mild desulfurization reaction was applied to a gas condensate real sample. The result revealed that 91.07% sulfur removal is achieved at 60 °C upon using an O/S molar ratio of 10:1.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Fuel - Volume 167, 1 March 2016, Pages 60–67
نویسندگان
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