کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
205978 | 461133 | 2015 | 9 صفحه PDF | دانلود رایگان |
• Carbonate-based ionic liquids can be used to remove naphthenic acids from crude oil.
• The reaction mechanism involves the formation of an ionic liquid-naphthenic acid complex.
• The complex can be reacted with carbonic acid to reform the ionic liquid.
• Recycling of the ionic liquid has been demonstrated.
A number of tetraalkylammonium methylcarbonate and hydrogencarbonate based ionic liquids are shown to be capable of reacting with the naphthenic acids contained in Doba crude oil via a neutralisation reaction. Spectral studies show that the ionic liquids neutralisation mechanism involves the formation of an ionic liquid-naphthenate complex, liberating methanol and carbon dioxide. Extraction of the neutralised complex into a separate methanol phase and subsequent regeneration using aqueous carbonic acid results in ∼70% of the ionic liquid being recovered for recycle. Isolation of the naphthenic acids shows that these make up to 0.85 wt% of the crude oil. Speciation of the naphthenic acids shows a mixture of monocyclic, through to tetracyclic structures with carbon numbers in the range C12–C40.
Journal: Fuel - Volume 146, 15 April 2015, Pages 60–68