Acid-catalyzed esterification of karanja (Pongamia pinnata) oil with high free fatty acids for biodiesel production

We report the production of a biodiesel fuel by acid-catalyzed esterification of high free fatty acid (FFA) karanja oil (KO). Pretreated KO was converted to biodiesel by a process of alkaline catalyzed transesterification. Optimum acid-catalyzed esterification was achieved using 1% Sulfated Zirconia (SZ) as a solid acid catalyst with a methanol-to-oil ratio of 9:1, temperature at 60 °C and reaction time of 2 h. During this process, FFA were converted into fatty acid methyl esters. The acid value of karanja oil was reduced to 1.3 mg KOH/g from 12.27 mg KOH/g, which confirmed the conversion. Consequently, this pretreatment reduces the overall complexity of the process and reduces the cost of producing biodiesel fuel.

► Biodiesel production by acid-catalyzed esterification of high FFA karanja oil.
► Esterification achieved in 2 h, with 1% SZ as catalyst, methanol:oil ratio 9:1, at 60 °C.
► Acid value of karanja oil was reduced to 1.3 mg KOH/g from 12.27 mg KOH/g.
► This pretreatment reduces the overall complexity of the process and cost of biodiesel.