Utilization of waste cockle shell (Anadara granosa) in biodiesel production from palm olein: Optimization using response surface methodology

The cockle shell, which is available in abundance, has no any eminent use and is commonly regarded as a waste, was utilized as a source of calcium oxide in catalyzing a transesterification reaction to produce biodiesel (methyl esters). A central composite design (CCD) was used to optimize the two major influential reaction variables: catalyst and methanol amount towards purity and yield of methyl esters. The analysis of variance (ANOVA) indicated that the catalyst has a positive influence on purity but negative on the yield. Meanwhile, the methanol/oil mass ratio showed a positive effect on both purity and yield. Using CCD, the optimum reaction conditions were found to be 4.9 wt.% of catalyst and 0.54:1 methanol/oil mass ratio. The prepared catalyst was capable of being reused under the suggested optimal conditions.

► Waste cockle shells were utilized as catalyst in transesterification of palm olein.
► Optimized conditions were 4.9 wt.% catalyst and 0.54:1 methanol/oil mass ratio.
► Catalyst was able to be reused at least for three times, with conversion above 97%.