کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
216262 1426264 2012 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Gas solubility of carbon dioxide and of oxygen in cyclohexanol by experiment and molecular simulation
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Gas solubility of carbon dioxide and of oxygen in cyclohexanol by experiment and molecular simulation
چکیده انگلیسی

Henry’s law constant data of carbon dioxide and of oxygen in liquid cyclohexanol are determined at temperatures between (303 and 392) K by means of a precise experimental high-pressure view-cell technique with a synthetic method. Furthermore, molecular simulations are carried out with a molecular mixture model, based on the modified Lorentz–Berthelot combination rule that contains one binary interaction parameter which is adjusted to one experimental Henry’s law constant for each binary mixture. The molecular model yields good results for the Henry’s law constant over the entire temperature range.


► Gas solubility measurements of carbon dioxide in liquid cyclohexanol are reported.
► Gas solubility measurements of oxygen in liquid cyclohexanol are reported.
► Henry’s law constant data is determined from the present experimental results.
► Very good agreement between experiment and molecular simulation is achieved.
► Ambiguity for the Henry’s law constant of oxygen in cyclohexanol is resolved.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: The Journal of Chemical Thermodynamics - Volume 49, June 2012, Pages 114–118
نویسندگان
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