کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
216327 | 1426282 | 2010 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Water as a solute in nitromethane: Effect of H2O–D2O isotope substitution on the solution volumetric properties between 278.15 K and 318.15 K
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Densities of solutions of H2O and D2O in nitromethane, with the solute mole fractions ranging up to 0.03, were measured with an error of 1.5 · 10−5 cm3 · mol−1 at (278.15, 288.15, 298.15, 308.15, and 318.15) K using a vibrating-tube densimeter. Apparent and partial volumes and isobaric expansibilities (down to the infinite dilution) of water isotopologues were calculated. The temperature-dependent behavior of D2O–H2O solute isotope effects on the molar quantities studied were described taking into account the structure- and interaction-related peculiarities of the dissolving medium in question.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: The Journal of Chemical Thermodynamics - Volume 42, Issue 12, December 2010, Pages 1458–1464
Journal: The Journal of Chemical Thermodynamics - Volume 42, Issue 12, December 2010, Pages 1458–1464
نویسندگان
Evgeniy V. Ivanov,