Dielectric data of binary mixtures of 1,2-butanediol with 2-ethyl-1-hexanol and 1,4-dioxane at T = (298.2, 308.2, and 318.2) K

Relative permittivity measurements were made on binary mixtures of (1,2-butanediol + 2-ethyl-1-hexanol) and (1,2-butanediol + 1,4-dioxane) for various concentrations at T = (298.2, 308.2, and 318.2) K. The molecular dipole moments were determined using Guggenheim–Debye method in the temperature range of (298.2 to 318.2) K. The variations of effective dipole moment and correlation factor, g, with the mole fraction in these materials were investigated using Kirkwood–Frohlich equation. The pure compounds showed a negative and small temperature coefficient of effective dipole moment. In order to obtain valuable information about heterogeneous interaction (interactions between the unlike molecules), the Kirkwood correlation factor, the Bruggeman dielectric factor and the excess permittivity were calculated. In addition, in order to predict the permittivity data of polar-apolar binary mixtures, five mixing rules were applied.

► Kirkwood g factor values indicate parallel dipole association for 1,2BD.
► Heterogeneous interactions are significant in (1,2BD + 2EH) mixtures.
► Mixing rules predict permittivity of 1,2BD in 1,4DX acceptably.