کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
216463 1426281 2011 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Thermodynamic temperature differences from the ITS-90 for the correction of thermodynamic property data
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Thermodynamic temperature differences from the ITS-90 for the correction of thermodynamic property data
چکیده انگلیسی

This paper purpose is to re-calculate thermodynamic or chemical–physical properties according to thermodynamic temperature T, where measured temperature values were obtained according to the ITS-90, T90 (or the reverse). The main aims of the calculations are: to remove the discontinuity of the first derivative at 273.16 K that is intrinsic in the ITS-90 definition; to use a single cubic spline to model the database of the available experimental data over the whole temperature range (2.37 to 1235) K, while maximising the medium-range smoothness of the correction function; to compute corrections using only local polynomial coefficients.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: The Journal of Chemical Thermodynamics - Volume 43, Issue 1, January 2011, Pages 75–79
نویسندگان
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