کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
217002 1426339 2006 11 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Isothermal (vapour + liquid) equilibrium for binary mixtures of (tetrahydrofuran + 1,1,2,2-tetrachloroethane or tetrachloroethene) at nine temperatures
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Isothermal (vapour + liquid) equilibrium for binary mixtures of (tetrahydrofuran + 1,1,2,2-tetrachloroethane or tetrachloroethene) at nine temperatures
چکیده انگلیسی

Vapour pressures of (tetrahydrofuran + 1,1,2,2-tetrachloroethane, or tetrachloroethene) at nine temperatures between T = 283.15 K and T = 323.15 K were measured by a static method. The reduction of the vapour pressures data to obtain activity coefficients and excess molar Gibbs energies was carried out by fitting the vapour pressure data to the Redlich–Kister polynomial according to Barker’s method. Excess molar volumes were also measured at T = 298.15 K. A comparative analysis about the thermodynamic behaviour of both systems is performed, in terms of hydrogen bonding and electron-donor–acceptor interactions, as well as the resonance effect in tetrachloroethene.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: The Journal of Chemical Thermodynamics - Volume 38, Issue 3, March 2006, Pages 348–358
نویسندگان
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