کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
217317 | 1426316 | 2008 | 9 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Part 2: Limiting apparent molar volume of organic and inorganic 1:1 electrolytes in (water + ethylammonium nitrate) mixtures at 298 K – Thermodynamic approach using Bahe–Varela pseudo-lattice theory Part 2: Limiting apparent molar volume of organic and inorganic 1:1 electrolytes in (water + ethylammonium nitrate) mixtures at 298 K – Thermodynamic approach using Bahe–Varela pseudo-lattice theory](/preview/png/217317.png)
Values of partial molar volumes at infinite dilution of 9 inorganic and 4 organic 1:1 electrolytes have been determined in (water + ethylammonium nitrate) (EAN) binary at 298.15 K throughout the composition scale. Our theoretical analysis shows that the values of partial molar volumes at infinite dilution of a solute in a binary are linked to those of the partial molar volumes of the components of mixed solvent. This applies to mixtures of molecular solvents as well as (water + ionic liquid) media. The use of the “pseudo-lattice theory” of Bahe recently supplemented Varela can be used for calculations and to obtain information about the interactions between 1:1 electrolytes as solutes at infinite dilution and their concentrated saline environment. We show that the “pseudo-lattice theory” allows accurate description of the behaviours of symmetrical tetraalkylammoniums bromide between the infinitely dilute state and concentrations higher than 2 mol · L−1.
Journal: The Journal of Chemical Thermodynamics - Volume 40, Issue 2, February 2008, Pages 146–154