کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
217330 1426316 2008 12 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Apparent molar volumes and apparent molar heat capacities of aqueous tetrahydrofuran, dimethyl sulfoxide, 1,4-dioxane, and 1,2-dimethoxyethane at temperatures from 278.15 K to 393.15 K and at the pressure 0.35 MPa
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Apparent molar volumes and apparent molar heat capacities of aqueous tetrahydrofuran, dimethyl sulfoxide, 1,4-dioxane, and 1,2-dimethoxyethane at temperatures from 278.15 K to 393.15 K and at the pressure 0.35 MPa
چکیده انگلیسی

We determined apparent molar volumes Vϕ at 278.15 ⩽ (T/K) ⩽ 368.15 and apparent molar heat capacities Cp,ϕ at 278.15 ⩽ (T/K) ⩽ 393.15 at p = 0.35 MPa for aqueous solutions of tetrahydrofuran at m from (0.016 to 2.5) mol · kg−1, dimethyl sulfoxide at m from (0.02 to 3.0) mol · kg−1, 1,4-dioxane at m from (0.015 to 2.0) mol · kg−1, and 1,2-dimethoxyethane at m from (0.01 to 2.0) mol · kg−1. Values of Vϕ were determined from densities measured with a vibrating-tube densimeter, and values of Cp,ϕ were determined with a twin fixed-cell, differential, temperature-scanning calorimeter. Empirical functions of m and T for each compound were fitted to our Vϕ and Cp,ϕ results.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: The Journal of Chemical Thermodynamics - Volume 40, Issue 2, February 2008, Pages 248–259
نویسندگان
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