کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
217361 1426326 2007 11 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Apparent molar volumes and apparent molar heat capacities of aqueous magnesium nitrate, strontium nitrate, and manganese nitrate at temperatures from 278.15 K to 393.15 K and at the pressure 0.35 MPa
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Apparent molar volumes and apparent molar heat capacities of aqueous magnesium nitrate, strontium nitrate, and manganese nitrate at temperatures from 278.15 K to 393.15 K and at the pressure 0.35 MPa
چکیده انگلیسی

Apparent molar volumes Vϕ and apparent molar heat capacities Cp,ϕ were determined at the pressure 0.35 MPa for aqueous solutions of magnesium nitrate Mg(NO3)2 at molalities m = (0.02 to 1.0) mol · kg−1, strontium nitrate Sr(NO3)2 at m = (0.05 to 3.0) mol · kg−1, and manganese nitrate Mn(NO3)2 at m = (0.01 to 0.5) mol · kg−1. Our Vϕ values were calculated from solution densities obtained at T = (278.15 to 368.15) K using a vibrating-tube densimeter, and our Cp,ϕ values were calculated from solution heat capacities obtained at T = (278.15 to 393.15) K using a twin fixed-cell, differential, temperature-scanning calorimeter. Empirical functions of m and T were fitted to our results, and standard state partial molar volumes and heat capacities were obtained over the ranges of T investigated.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: The Journal of Chemical Thermodynamics - Volume 39, Issue 4, April 2007, Pages 550–560
نویسندگان
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