کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
217972 463176 2016 11 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis of hexagonal CoAl-layered double hydroxide nanoshales/carbon nanotubes composite for the non-enzymatic detection of hydrogen peroxide
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Synthesis of hexagonal CoAl-layered double hydroxide nanoshales/carbon nanotubes composite for the non-enzymatic detection of hydrogen peroxide
چکیده انگلیسی


• Hexagonal CoAl-layered double hydroxide nanoshales/multiwall carbon nanotubes nanocomposite was synthesized.
• The nanocomposite showed an enhanced non-enzymatic detection performance toward hydrogen peroxide.

A nanocomposite comprising hexagonal CoAl-layered double hydroxide nanoshales with multiwall carbon nanotubes (MWCNTs) was synthesized by reflux heating. The nanocomposite was then applied to modify a carbon paste electrode. The modified electrode was then applied to fabricate a non-enzymatic hydrogen peroxide sensor. Hydrogen peroxide was electrocatalytically oxidized on the modified electrode surface, while its electroreduction was performed by an enhanced direct electron transfer to the electrode surface. The catalytic rate constants of the hydrogen peroxide electrooxidation were processed by an active cobalt species, and the diffusion coefficient of hydrogen peroxide was reported. An amperometric method was developed for determination of hydrogen peroxide based on its electrocatalytic oxidation with a sensitivity of 118.0 mA dm3 mol− 1 cm− 2 and a limit of detection of 10 μmol dm− 3. In addition, amperometric method based on hydrogen peroxide electroreduction had a sensitivity of 42.0 mA dm3 mol− 1 cm− 2 and a limit of detection of 40 μmol dm− 3. The sensor had the advantages of high activity and sensitivity, with a simple fabrication method without complications of immobilization steps and using any enzyme or reagent.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Electroanalytical Chemistry - Volume 768, 1 May 2016, Pages 134–144
نویسندگان
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