کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
218124 463184 2015 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Facile synthesis of flexible gold film electrodes for highly selective photoelectrochemical sensing of ascorbic acid
ترجمه فارسی عنوان
سنتز تکه ای از الکترودهای فیلم انعطاف پذیر طلایی برای سنجش عکس العمل الکتروشیمیایی بسیار اسیدی اسید آسکوربیک
کلمات کلیدی
سنسورهای عکس الکتروشیمیایی، اسید اسکوربیک، الکترودهای فیلم طلایی، نانولوله های کربنی، فولرین
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
چکیده انگلیسی


• A gold–PET film electrode (GPETFE) was fabricated by a simple electroless method.
• GPETFE modified with a carbon photovoltaic material creates a new PEC sensor.
• This PEC sensor was applied to the selective detection of AA in food samples.

A simple electroless method for fabricating inexpensive and flexible gold film electrodes was reported. The method was established by the spontaneous adsorption of gold nanoparticle (GNP) seeds on polyethylene terephthalate (PET) film substrates and the self-catalytic growth of the adsorbed GNP seeds into conductive gold layers. The resulting gold–PET composite film electrode (GPETFE) not only possessed better flexibility and conductivity as compared with the widely used indium tin oxide (ITO) substrates, but also exhibited apparently higher conversion efficiency for photoelectrochemical (PEC) sensing. As a result, the modification of GPETFE by a hybrid photovoltaic material that comprised carboxylated multiwalled carbon nanotubes, Congo red and fullerene (MWNTCOOH-CR-C60) created a disposable and highly selective thin-film PEC sensor of ascorbic acid (AA), i.e., the PEC response of 1.0 mM AA was hardly influenced by interferents like 100 folds of dopamine (DA) and hydroquinone (H2Q). The produced PEC sensor also showed a sensitive PEC response toward AA with wide calibration ranges from 2.5 μM to 2.5 mM and a low detection limit of 0.5 μM (S/N = 3), which was successfully applied to the detection of AA in real samples like fruits, vegetables and beverages.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Electroanalytical Chemistry - Volume 759, Part 1, 15 December 2015, Pages 2–7
نویسندگان
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