کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
218816 463220 2014 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Voltammetry at porous electrodes: A theoretical study
ترجمه فارسی عنوان
ولتاژ سنجی در الکترودهای متخلخل: یک مطالعه نظری
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
چکیده انگلیسی


• Chronoamperometry and cyclic voltammetry at porous electrodes is simulated.
• Electrodes are considered to be a series of interconnected spherical voids.
• Diffusion within the voids and bulk diffusion is considered to be decoupled.
• A new approach to estimate heterogeneous rate constants is proposed.

Theory is presented to simulate both chronoamperometry and cyclic voltammetry at porous electrodes fabricated by means of electro-deposition around spherical templates. A theoretical method to extract heterogeneous rate constants for quasireversible and irreversible systems is proposed by the approximation of decoupling of the diffusion within the porous electrode and of bulk diffusion to the electrode surface.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Electroanalytical Chemistry - Volumes 720–721, 15 April 2014, Pages 92–100
نویسندگان
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