The electrochemical copolymerization of diphenylamine and p-phenylenediamine and its use as a modified electrode for amperometric determination of iodate

• This is the first report of synthesis of copoly(diphenylamine and p-phenylenediamine).
• The fabricated copolymer was characterized by FT-IR, CHNS, EDX, AFM and SEM.
• This copolymer can be a good candidate for fabricating a novel iodate sensor.

In this paper, copolymerization of diphenylamine with p-phenylenediamine was carried out in aqueous sulfuric acid by means of cyclic voltammetric sweep. The obtained copolymer was characterized by cyclic voltammetry (CV), Fourier transform infrared (FTIR), CHNS, energy-dispersive X-ray (EDX) spectroscopy, scanning electron microscopy (SEM) and atomic force microscopy (AFM). Electrochemical experiments indicated that the copolymer modified electrode exhibited an excellent sensitivity towards the reduction of iodate, which can be attributed to the electrical conductivity, nanoporous structure of the copolymer composite and an electrostatic interaction between the cationic oxidized (p-doped) copolymer and the anionic iodate. The electrochemical behavior of iodate has been investigated by amperometry and cyclic voltammetry at copolymer modified electrode. Amperometry revealed that there existed a good linear relationship between peak current with the concentration in the range of 50–550 μM and the detection limit of 0.8 μM. This composite film was also successfully applied in determination of iodate in urine.

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