کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
218962 463230 2013 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Square wave anodic stripping voltammetric analysis of lead and cadmium utilizing titanium dioxide/zirconium dioxide carbon paste composite electrode
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Square wave anodic stripping voltammetric analysis of lead and cadmium utilizing titanium dioxide/zirconium dioxide carbon paste composite electrode
چکیده انگلیسی

Recently, our research group has developed a novel carbon paste composite electrode, in which titanium dioxide/zirconium dioxide was incorporated into graphite carbon paste, to detect cadmium and lead in aqueous solution via cyclic voltammetry. In the current work, the newly developed titanium dioxide/zirconium dioxide carbon paste composite electrode was used to quantify lead and cadmium, individually and simultaneously, utilizing square wave anodic stripping voltammetry. In addition to optimization of multiple stripping analysis parameters, trace levels quantification of both metals was attempted. Using the mentioned titanium dioxide/zirconium dioxide carbon paste composite electrode, the detection limits, in modeling solutions, for Pb and Cd were estimated to be 0.48 ppb and 0.77 ppb, respectively. Furthermore, reproducibility of analytical stripping current signal was also calculated and expressed as relative standard deviation for both metals, 3.8% for Cd and 2.5% for Pb (n = 10). The proposed sensor was also tested in river water and well water samples to illustrate its potential for real world application. Moreover, scanning electron microscopy was employed to investigate and characterize the electrode surface morphology.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Electroanalytical Chemistry - Volume 711, 15 December 2013, Pages 45–52
نویسندگان
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