کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
219807 | 463297 | 2011 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Substituent and solvent dependence of the one-electron reduction of 5-substituted-N-methylisatins in aprotic solvents
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
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چکیده انگلیسی
Potentials for the one-electron reduction of nine 5-substituted N-methylisatins were measured in ten aprotic solvents by cyclic voltammetry. Best-fit Hammett σ substituent constants were determined and used in Hammett plots to determine reaction constants, ρ, for all solvents. Correlations of solvent polarity parameters with the Hammett ρ values and with measured reduction potentials suggest that empirical solvent parameters that reflect the strength of solvent molecular cohesive forces and solvent Lewis acidity are important predictors of the ability of solvent to facilitate the one-electron reduction of isatins in aprotic media by stabilizing the radical anion reduction products.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Electroanalytical Chemistry - Volume 651, Issue 2, 1 February 2011, Pages 228–232
Journal: Journal of Electroanalytical Chemistry - Volume 651, Issue 2, 1 February 2011, Pages 228–232
نویسندگان
Andrew Yeagley, AuBrei J. Weigand-Heller, Derek Hinds, Ashley K. Gerrish, Corey D. Weaver, Owen A. Moe,