کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
219835 | 463299 | 2010 | 11 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Facilitated anion transfer reactions across oil∣water interfaces
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
In this paper we present the general equations for a model of anion transfer reactions across the oil∣water interface assisted by a neutral ligand. Our analysis mainly focuses on the effect of water autoprotolysis. The equations reported here allow us to simulate the system under a variety of possible conditions. The formation of complex with j:k anion-to-ligand stoichiometry is analyzed. Three different models are compared: buffered solutions (BASA model) and unbuffered solutions with and without considering water autoprotolysis (UBASA and UBAS model respectively). Moreover, the analytical relationships for the BASA model between half-wave potential and the initial concentration of anion and ligand are developed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Electroanalytical Chemistry - Volume 643, Issues 1–2, 1 May 2010, Pages 20–30
Journal: Journal of Electroanalytical Chemistry - Volume 643, Issues 1–2, 1 May 2010, Pages 20–30
نویسندگان
S.A. Dassie,