کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
219974 | 463309 | 2010 | 11 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Fabrication, characterization and application of graphite ring ultramicroelectrodes for kinetic studies of fuel cell reactions under high mass-transport rates Fabrication, characterization and application of graphite ring ultramicroelectrodes for kinetic studies of fuel cell reactions under high mass-transport rates](/preview/png/219974.png)
This work describes the preparation of nanocrystalline-graphite inlaid ring ultramicroelectrodes (UMEs) with inner diameters larger than 0.3 μm and thicknesses as low as a few nanometers. The geometric parameters of these UMEs were determined by a combination of optical microscopy and cyclic voltammetry data. These UMEs permit to establish mass-transport rates as large as those obtained on nanometer-sized hemispherical UMEs. They have very low electrochemical activity in acid and can function very well as catalyst supports for kinetic studies of fuel cell reactions such as the hydrogen oxidation reaction (hor). In order to demonstrate the outstanding utility of these electrodes, compact Pt films were electrodeposited on graphite ring UMEs and used to carry out a kinetic study of the hor in acid medium.
Journal: Journal of Electroanalytical Chemistry - Volume 642, Issue 1, 1 April 2010, Pages 41–51