کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
220336 463328 2008 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Electrochemical properties and electronic structures of two neutral nickel bis(1,2-dithiolene) complexes
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Electrochemical properties and electronic structures of two neutral nickel bis(1,2-dithiolene) complexes
چکیده انگلیسی

The synthesis, spectroscopic and electrochemical characterizations of two neutral bisdithiolene nickel complexes are described. Electrochemical reversibility and bandgap have been measured by different techniques. The influence of the nature and length of the alkyl chain, the type of electrode (Pt microdisk for solutions, ITO-coated glass, Pt wire, and CME (cavity microelectrode) for condensed state) and the solvent have been investigated. Optical transmission measurements in the visible–near-IR (VIS–NIR) region allowed the determination of the optical bandgap.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Electroanalytical Chemistry - Volume 624, Issues 1–2, 1 December 2008, Pages 84–90
نویسندگان
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