کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
220467 463334 2008 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
The cyclic renewable mercury film silver based electrode for determination of manganese(II) traces using anodic stripping voltammetry
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
The cyclic renewable mercury film silver based electrode for determination of manganese(II) traces using anodic stripping voltammetry
چکیده انگلیسی

Application a new type of working electrode – cyclic renewable mercury film silver based electrode (Hg(Ag)FE) – for manganese(II) traces detection via differential pulse anodic stripping voltammetry (DP ASV) is reported. The preparation of the Hg(Ag)FE is very simple and economically more acceptable; the electrode has a very good stability, and the renovation of the surface is easy. The Hg(Ag)FE electrode is characterized by very good surface reproducibility (⩽2%) and long-term stability (more than 2000 measurement cycles). The effects of various factors such as: pre-concentration potential and time, pulse height, step potential, surface areas of the working electrode are optimized. The calibration graph is linear from 10 nM (0.55 μg L−1) to over 260 nM (14.3 μg L−1) for an accumulation time of 15 s, with correlation coefficient of 0.9995. For a Hg(Ag)FE with a surface area of 7.1 mm2 the detection limit for an accumulation time of 120 s is as low as 0.3 nM (16 ng L−1). The repeatability of the method at a concentration level of the analyte as low as 50 nM 2.7 μg L−1, expressed as RSD is 2.6% (n = 7). The proposed method was successfully applied and validated by studying the certified reference material TMRAIN-95 and simultaneously recovery of Mn(II) from spiked water and snow samples.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Electroanalytical Chemistry - Volume 621, Issue 1, 1 September 2008, Pages 43–48
نویسندگان
, , ,