کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
220657 | 463345 | 2008 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Voltammetric study of the interfacial electron transfer between bis(phthalocyaninato)lutetium in 1,2-dichloroethane and hexacyanoferrate in water
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The electron transfer reaction between bis(phthalocyaninato)lutetium(III) ([Lu(pc)2]0) in 1,2-dichloroethane (1,2-DCE) and hexacyanoferrate(II/III) redox couple ([Fe(CN)6]4−/3−) in water (W) at the interface was studied by the use of normal pulse voltammetry and ac-voltammetry. The ac-voltammetric results have reconfirmed that the electron transfer reaction between [Lu(pc)2] in 1,2-DCE and [Fe(CN)6]4−/3− in W takes place by way of the heterogeneous electron transfer at the interface, but not by the homogeneous electron transfer reaction associated with the ion transfer of redox species across the interface. The kinetic parameters of the heterogeneous electron transfer reaction at the interface were determined.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Electroanalytical Chemistry - Volume 614, Issues 1–2, 15 March 2008, Pages 61–66
Journal: Journal of Electroanalytical Chemistry - Volume 614, Issues 1–2, 15 March 2008, Pages 61–66
نویسندگان
Hirosuke Tatsumi, Hajime Katano,