کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
221037 463367 2007 10 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Electrodeposition at the liquid/liquid interface: The chronoamperometric response as a function of applied potential difference
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Electrodeposition at the liquid/liquid interface: The chronoamperometric response as a function of applied potential difference
چکیده انگلیسی

The electrodeposition of Pd at the interface between two immiscible electrolyte solutions has been investigated using chronoamperometric techniques, under conditions of variable applied overpotential. An alumina membrane-templated interface has been used as a means to circumvent the agglomeration phenomena shown previously to affect deposit growth at this type of interface. Palladium deposition, from aqueous solutions of tetrachloropalladate, was induced by electron transfer from an organic phase electron donor (butylferrocene). The resultant data has been interpreted in terms of classical models, previously developed for amperometric deposition on solid electrode surfaces.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Electroanalytical Chemistry - Volume 599, Issue 2, 15 January 2007, Pages 323–332
نویسندگان
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