کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
221152 | 463376 | 2006 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Electrolytic partial fluorination of organic compounds. Part 85. Anodic gem-difluorination of hydrazones using Et4NI as a mediator
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Electrolytic partial fluorination of organic compounds. Part 85. Anodic gem-difluorination of hydrazones using Et4NI as a mediator Electrolytic partial fluorination of organic compounds. Part 85. Anodic gem-difluorination of hydrazones using Et4NI as a mediator](/preview/png/221152.png)
چکیده انگلیسی
Anodic gem-difluorination of hydrazones in Et4NF-5HF/CH2Cl2 in the presence of Et4NI was successfully carried out to provide the corresponding gem-difluorinated products in moderate to good yields. On the other hand, no gem-difluorinated products were obtained in the absence of Et4NI. Although a catalytic current was not observed in the cyclic voltammetry of Et4NI in the presence of a hydrazone, a controlled potential electrolysis of the hydrazone showed that Et4NI acted as a mediator in the anodic gem-difluorination of hydrazones.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Electroanalytical Chemistry - Volume 593, Issues 1–2, 1 August 2006, Pages 43–46
Journal: Journal of Electroanalytical Chemistry - Volume 593, Issues 1–2, 1 August 2006, Pages 43–46
نویسندگان
Toshiki Tajima, Nanae Imai, Atsushi Nakajima, Hitoshi Kurihara, Toshio Fuchigami,