High pressure densities of carbon dioxide + dipentaerythritol hexaheptanoate: New experimental setup and volumetric behavior

To perform an appropriate selection of the lubricants in air conditioned systems working with carbon dioxide as refrigerant, the thermodynamic behavior of the CO2 + lubricant systems must be well known. In this work we present a new setup to prepare compressed gas–liquid mixtures and to determine the high pressure density by using an automated densimeter HPM and two syringe pumps. To analyze the reliability of the procedure proposed, we have determined the densities and mixing volumes of four CO2 + n-decane mixtures. We have found a good agreement with previous literature data. In addition new density values are reported for the binary system CO2 + dipentaerythritol hexaheptanoate (DiPEC7) at several temperatures and pressures from 10 MPa to 120 MPa.

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• New setup to prepare compressed gas–liquid mixtures and to determine their densities.
• We present new density values for four compressed CO2 + n-decane mixtures up to 120 MPa.
• Excellent agreement of these densities with literature data shows the set reliability.
• New volumetric data for a compressed CO2 + polyolester system are presented.