کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
231397 | 1427434 | 2010 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Tandem Staudinger-Aza-Wittig reaction in supercritical CO2: Synthesis of a pharmaceutical interest compound
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Tandem Staudinger-Aza-Wittig reaction in supercritical CO2: Synthesis of a pharmaceutical interest compound Tandem Staudinger-Aza-Wittig reaction in supercritical CO2: Synthesis of a pharmaceutical interest compound](/preview/png/231397.png)
چکیده انگلیسی
The aim of this research was to investigate the capability of using supercritical CO2 (scCO2) as reagent and solvent in the synthesis of pharmaceutical cyclodextrinyl derivatives in smooth reaction conditions. In this way we have followed the kinetics of a synthesis which was previously realized in DMF, by using tandem Staudinger-Aza-Wittig (S.A.W.) reaction in scCO2 at 200 bars pressure in a 100 mL reactor. The results show that the reaction in scCO2 showed a second order kinetics with the yield of 92%.
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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: The Journal of Supercritical Fluids - Volume 53, Issues 1–3, June 2010, Pages 60–63
Journal: The Journal of Supercritical Fluids - Volume 53, Issues 1–3, June 2010, Pages 60–63
نویسندگان
Alexandre Scondo, Florence Dumarcay, Alain Marsura, Danielle Barth,