Selective flotation separation of spodumene from feldspar using new mixed anionic/cationic collectors

• NaOL/DTAC shows a high selectivity for flotation of spodumene from feldspar.
• The optimum molar ratio of NaOL and DTAC in mixed collectors is found to be 9:1.
• NaOL/DTAC is less affected by temperature.
• NaOL/DTAC consumption decrease by two-thirds as compared to mixed fatty acid.

The selectivity in flotation separation of spodumene from other pegmatic aluminosilicates such as feldspar and mica, using a single fatty acid anionic collector, is found to be very difficult. It is attributed to the same surface Al site for interaction with fatty acid. In this study, a collector mixture of sodium oleate (NaOL) and dodecyl trimethyl ammonium chloride (DTAC) demonstrates a high selectivity for the flotation of spodumene from feldspar. The influences of important factors such as molar ratio of the mixed collectors, dosages of calcium chloride, sodium hydroxide and sodium carbonate, and pulp temperature on spodumene and feldspar flotation using the mixed collectors have been investigated through micro-flotation tests. The optimum molar ratio of NaOL and DTAC is found to be 9:1. Sodium hydroxide has to be used as a pH regulator. Without the use of depressants, no selectivity is observed as the flotation of spodumene and feldspar are activated by Ca2+. Sodium carbonate must be used as depressant of feldspar. A comparison of the flotation for a lithium pegmatite ore using mixed fatty acid soaps and mixed anionic/cationic collectors (NaOL/DTAC) was carried out by the batch flotation tests. The results indicated that NaOL/DTAC decrease collector consumption by two-thirds. The recovery and grade of Li2O concentrates increase by 4.93% and 0.31%, respectively.

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