Leaching of limonitic laterite ore by acidic thiosulfate solution

Cobalt is usually recovered as a by-product of copper and nickel processing, and only a small amount of cobalt is derived from laterites although a vast majority of cobalt resources in them. The exploitation of limonitic laterite containing high content of cobalt is becoming increasingly important. The mineralogy of a limonitic laterite ore was characterized by environmental scanning electron microscope (ESEM) and X-ray diffraction (XRD) in this paper. The results show that nickel occurs in goethite mainly, while cobalt is predominantly associated with manganiferous minerals. Thiosulfate is found to be able to selectively leach cobalt from limonitic laterite in the presence of sulfuric acid, and 91% Co, 22% Ni, 10% Fe are leached from an ore containing 0.13% Co, 1.03% Ni within the first 5 min at 90 °C under the conditions of 10 g/L sodium thiosulfate, 8% (w/w) sulfuric acid and 10:1 L/S ratio. The leaching kinetics of Mn and Co by acidic sodium thiosulfate solution can be characterized by the Avrami equation. In acidic solution, thiosulfate readily decomposes into sulfur and sulfur dioxide as intermediary reagents to reduce pyrolusite (MnO2) and goethite (FeOOH); therefore, nickel and cobalt associated with goethite and pyrolusite respectively are extracted due to reduction dissolution. Furthermore, cobalt is selectively leached over iron and nickel because pyrolusite is preferentially reduced by acidic thiosulfate rather than goethite. The novel process may give an alternative method to selectively recover cobalt as the primary product from limonitic laterites at atmospheric pressure.

Effects of leaching time on the metals extractions by acidic thiosulfate solution. Thiosulfate is found to be able to selectively leach cobalt from limonitic laterite in the presence of sulfuric acid within the first 5 min at atmospheric pressure.Figure optionsDownload as PowerPoint slideHighlights
► In laterite, Co is almost exclusively associated with pyrolusite, while Ni mainly occurs in goethite.
► Acidic thiosulfate solution is able to selectively extract cobalt.
► 91% of Co can be leached within the first 5 min at 90 °C by acidic thiosulfate solution.
► Thiosulfate plays the role of reductive dissolving pyrolusite and goethite.
► The leaching kinetics of Mn and Co can be characterized by the Avrami equation.