کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
2449568 | 1554083 | 2016 | 9 صفحه PDF | دانلود رایگان |
• Good correlations were found between Raman spectra and gross fatty acid (FA) parameters.
• Good correlations were found between Raman spectra and most individual FAs.
• Predictions of individual FAs were based on co-variance with gross FA parameters.
• A new method was developed to characterize the non-targeted calibrations.
• Backfat samples were discriminated based on fat layers and feeding regimes.
This study investigates how Partial Least Squares regression models for predicting individual fatty acids (FAs) and total FA parameters depend on Raman spectral variation associated with the iodine value in pork backfat. The backfat was sampled from pigs, which were fed with different dietary fat sources and levels. Good correlations between the Raman spectra and the total FA composition parameters and most individual FAs were obtained (RCV2 = 0.78–0.90). However, the predictions of the individual FAs are indirect and to a high degree depend on co-variance with the total FA parameters. A new procedure was demonstrated for identifying and characterizing such indirect or non-targeted calibrations. This information is very useful when Raman spectroscopy or other vibrational spectroscopic techniques are used to predict non-targeted quality parameters such as individual FAs as they may lead to inaccurate predictions of future sample if the underlying covariance structure is changed e.g. by new dietary regimes or genotypes.
Journal: Meat Science - Volume 111, January 2016, Pages 18–26