کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
42106 45911 2010 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Kinetics and mechanism of partial oxidation of ethane to ethylene and acetic acid over MoV type catalysts
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Kinetics and mechanism of partial oxidation of ethane to ethylene and acetic acid over MoV type catalysts
چکیده انگلیسی

A kinetics study for the partial oxidation of ethane to ethylene and acetic acid is performed over MoV type catalysts. It is established that ethylene is the primary product and acetic acid and carbon oxides are secondary products. Formation of acetic acid product increases significantly with the co-feeding of water into the reactor. The elementary steps of the reaction network are formulated using a two-site Eley-Rideal-Redox (ERR) model, which includes the participation of water in the reaction scheme through surface OH− groups. The derived ERR model predicts the experimental data satisfactorily.

A kinetics study for the partial oxidation of ethane to ethylene and acetic acid is performed over MoV type catalysts. It is established that ethylene is the primary product and acetic acid and carbon oxides are secondary products. Formation of acetic acid product increases significantly with the co-feeding of water. The elementary steps of the reaction network are formulated using a two-site Eley-Rideal-Redox (ERR) model.Figure optionsDownload high-quality image (25 K)Download as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Catalysis A: General - Volume 375, Issue 1, 26 February 2010, Pages 17–25
نویسندگان
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