کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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42403 | 45923 | 2009 | 8 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: KyMg1−xZn1+xO3 as a heterogeneous catalyst in the transesterification of palm oil to fatty acid methyl esters KyMg1−xZn1+xO3 as a heterogeneous catalyst in the transesterification of palm oil to fatty acid methyl esters](/preview/png/42403.png)
An active heterogeneous catalyst of the type KyMg1−xZn1+xO3 that separates easily from an ester product mixture has been developed. The catalytic efficiency was studied with the transesterification of palm oil into fatty acid methyl esters. The catalyst was thermally treated at 461 °C for 4 h. A typical K2Mg0.34Zn1.66O3 oxide was characterized with powder X-ray diffraction and infrared Fourier transform, and its microstructure was studied by the use of scanning electron microscopy. The properties studied provided insight into the catalytic performance of the catalyst. The optimum conditions were obtained by varying parameters such as methanol to oil ratio, catalyst loading, temperature and time. The highest ester conversion of 87% was achieved under atmospheric pressure in 5 h at 188 °C using 64 g of refined palm oil, 38 g of methanol and 2.3 wt% catalyst dosage. The results showed that a synergetic effect of active components was responsible for its high activity.
An active heterogeneous catalyst has been developed. The catalytic efficiency was studied with the transesterification of palm oil into fatty acid methyl esters. Thermal treatment of the catalyst at 461 °C for 4 h was carried out. The results showed that a synergetic effect of active components was responsible for its high activity.Figure optionsDownload as PowerPoint slide
Journal: Applied Catalysis A: General - Volume 371, Issues 1–2, 15 December 2009, Pages 191–198