Catalytic behaviour of nickel and iron metal contaminants of an FCC catalyst after oxidative and reductive thermal treatments

The catalytic effects of nickel and iron deposited on an FCC (fluidized catalytic cracking) catalyst via metal naphthenates were studied in a micro activity test (MAT) unit after both oxidative and reductive treatments of the catalyst samples.The dehydrogenation activity of nickel was found to be close to the dehydrogenation activity of vanadium – and not several times higher than that of vanadium as is often reported – when deposited on the commercial FCC catalyst used in this study followed by steam deactivation (oxidative treatment) at 760 °C. However, the dehydrogenation activity of nickel was significantly intensified after post-treatment with a CO/N2 mixture at this temperature (reductive treatment).The results show that iron did not have a dehydrogenation activity after steaming, but had a significant dehydrogenation activity after steaming when followed by exposure to the CO/N2 mixture at 760 °C. The results indicate that the presence of deposited iron was inducing an additional catalytic cracking activity for the FCC catalyst.It was observed that co-impregnation of equal loadings of nickel, iron and vanadium on the FCC catalyst led to a considerably higher dehydrogenation activity than could be expected from the catalytic behaviour of the separate elements. The dehydrogenation activity was however slightly reduced by the reductive treatment as the reduced dehydrogenation activity from the lower oxidation state of vanadium (V3+) more than compensated the increased dehydrogenation activity of iron and nickel. A slightly increased gasoline production after the reductive treatment of the co-impregnated sample was a result of the increased production of gasoline from the FCC catalyst itself, which more than compensated for the reduced gasoline production from nickel.

The catalytic effects of impregnated nickel and iron via naphthenates on an FCC catalyst followed by steam deactivation were studied after oxidative and reductive treatments at 760 °C.The dehydrogenation activity of nickel was found to be close to the dehydrogenation activity of vanadium for the FCC catalyst used in this study and not several times higher than that of vanadium as is often reported.Hydrogen yield for FCC samples impregnated with 3000 ppm Ni or Fe followed by deactivation (Ni-ox and Fe-red) or deactivation and reductive treatment (Ni-red and Fe-red).Figure optionsDownload as PowerPoint slide