Mineral chemical constraints on the petrogenesis of mafic and intermediate volcanic rocks from the Erciyes and Hasandağ volcanoes, Central Turkey

Hasandağ and Erciyes stratovolcanoes, which produced both calc-alkaline and alkaline eruptive products, are the two important volcanic complexes in Central Anatolia. There are three geochemical evolution stages in the history of the Hasandağ strato volcanic complex: (1) Keçikalesi tholeiitic, (2) Hasandağ calc-alkaline and (3) Hasandağ alkaline. Volcanologic and petrologic characteristics of the Hasandağ and Erciyes calc-alkaline series show that water played an important role on the genesis of these rocks. These rocks are phenocryst-rich with vesicular texture, and contain hydrous mineral phases. The approximate pressure and temperature estimates obtained from the mineral chemistry studies of the Hasandağ strato volcanic complex indicate crystallization temperature of 1100 °C with 2.5–3.4 kbar pressure interval for the first stage of Keçikalesi tholeiitic volcanism, and about 850 °C temperatures with 4.3–9.6 kbar pressure intervals for the second stage of Hasandağ calc-alkaline volcanism.The geochemical evolution of Erciyes volcanic complex also exhibits three distinct evolutionary stages: (1) Koçdağ alkaline, (2) Koçdağ calc-alkaline and (3) Erciyes calc-alkaline. The temperature of Koçdağ alkaline volcanism is 1097–1181 °C and in a range of 5.1–6.7 kbar pressure, for Koçdağ calc-alkaline volcanism 850–1050 °C temperature to 2.0–6.6 kbar pressure interval, and for Erciyes calc-alkaline volcanism about 950 °C temperature, to 3.2–7.9 kbar pressure intervals were calculated. Polybaric origin of magma chambers for calc-alkaline and alkaline rocks and disequilibrium parameters observed in phenocrysts indicate that the rocks were affected by magma mixing processes in crustal magma chambers. The disequilibrium features of amphibole and plagioclase phenocrysts in these rocks point the latent heat in magma chambers and periodic recharging with mafic magma chambers and also show that magmas reequilibrate before the eruption.