کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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4421614 | 1308518 | 2009 | 6 صفحه PDF | دانلود رایگان |
The effects of bovine manure (BM) on the degradation of hexazinone and formation of three of its major metabolites were investigated in sandy loam soil. The degradation half-life of hexazinone was 29.6 days in unamended soil, while it decreased to 21.8 days in BM-amended soil. The major metabolites formed in unamended soil were [3-cyclohexyl-6-(methylamino)-1-methyl-1,3,5-triazine-2,4(1, 3H)-dione] (metabolite A) and [3-cyclohexyl-1-methyl-1,3,5-triazine-2,4,6(1, 3, 5H)-trione] (metabolite C), while metabolite B [3-(4-hydroxycyclohexyl)-6-(dimethylamino)-1-methyl-1,3,5-triazine-2,4(1, 3H)-dione] was not detected over the entire experimental period. However, in BM-amended soil, metabolite B was detected at 20 and 40 days after incubation, suggesting that BM contributed to formation of this metabolite. N-demethylation, removal of the dimethylamino group with formation of a carbonyl group at the 6-position of the triazine ring appeared to be the principal mechanisms involved in hexazinone metabolism in unamended soil. However, hydroxylation at the 4-positon of the cyclohexyl group as well as the above two modes were the principal pathways in BM-amended soil.
Journal: Ecotoxicology and Environmental Safety - Volume 72, Issue 1, January 2009, Pages 93–98