Using hydrochemical data and modelling to enhance the knowledge of groundwater flow and quality in an alluvial aquifer of Zagreb, Croatia

• The Zagreb aquifer is the largest utilised source of groundwater in northern Croatia.
• Better water quality was observed in the deeper parts compare to the shallow.
• The hydrochemical characteristics indicate stratification of the aquifer system.
• The influence of the Sava River on aquifer depends on specific hydrological conditions.

The Zagreb alluvial aquifer system is located in the southwest of the Pannonian Basin in the Sava Valley in Croatia. It is composed of Quaternary unconsolidated deposits and is highly utilised, primarily as a water supply for the more than one million inhabitants of the capital city of Croatia. To determine the origin and dynamics of the groundwater and to enhance the knowledge of groundwater flow and the interactions between the groundwater and surface water, extensive hydrogeological and hydrochemical investigations have been completed. The groundwater levels monitored in nested observation wells and the lithological profile indicate that the aquifer is a single hydrogeologic unit, but the geochemical characteristics of the aquifer indicate stratification. The weathering of carbonate and silicate minerals has an important role in groundwater chemistry, especially in the area where old meanders of the Sava River existed. Groundwater quality was observed to be better in the deeper parts of the aquifer than in the shallower parts. Furthermore, deterioration of the groundwater quality was observed in the area under the influence of the landfill. The stable isotopic composition of all sampled waters indicates meteoric origin. NETPATH-WIN was used to calculate the mixing proportions between initial waters (water from the Sava River and groundwater from “regional” flow) in the final water (groundwater sampled from observation wells). According to the results, the mixing proportions of “regional” flow and the river water depend on hydrological conditions, the duration of certain hydrological conditions and the vicinity of the Sava River. Moreover, although the aquifer system behaves as a single hydrogeologic unit from a hydraulic point of view, it still clearly demonstrates geochemical stratification, which could be a decisive factor in future utilisation strategies for the aquifer system.