Aldehyde concentrations in wet deposition and river waters

The process of pollutants removal from the atmosphere can be responsible for the appearance of aldehydes in surface waters. We observed that formaldehyde, acetaldehyde, propanal, glyoxal, methylglyoxal and acetone were commonly present in precipitations as well as in surface water samples, while semi-volatile and poorly soluble aldehydes as nonanal and decanal were observed seasonally. Particularly high level of carbonyls concentration was noted after periods of drought and at the beginning of rainy periods. We estimated that ca. 40% of aldehydes from wet precipitations were delivered into river waters. The level of carbonyl concentration in river was positively correlated with specific local meteorological conditions such as solar radiation and ozone concentration, in contrast, there was negative correlation between aldehyde concentration in the river samples and the precipitation intensity.

► Atmosphere pollutants are responsible for the appearance of aldehydes in surface waters.
► Volatile aldehydes are commonly present in precipitations as well as in surface waters.
► Semi-volatile and poorly soluble aldehydes as nonanal and decanal were observed seasonally.
► High concentration of carbonyls were noted after periods of drought and at the beginning of rain.
► Carbonyl concentration in river is correlated to meteorological conditions.